Barium Diphenylamine Sulphonate – Product identifier
Trade name: Barium Diphenylamine Sulphonate

1 Identification

2 Barium Diphenylamine Sulphonate – Hazard(s) identification
· Classification of the substance or mixture
H302 + H332: Harmful if swallowed.
Label elements
·
GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms
·
Signal word Warning
· Hazard statements
Harmful if swallowed.
· Precautionary statements
Do not breathe dusts or mists. Wash thoroughly after handling.
Wear protective gloves/protective clothing/eye protection/face protection. If swallowed: Rinse mouth. Do NOT induce vomiting.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a poison center/doctor. Specific treatment (see on this label).
Chemical characterization: Mixtures
Description: Mixture of the substances listed below with nonhazardous additions.
Description of first aid measures
General information: Immediately remove any clothing soiled by the product.
After inhalation: Fresh air, immediately calla physician.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact: Rinse eye for several minutes under running water. Then consult a doctor.
After swallowing: Drink copious amounts of water and provide fresh air. Immediately call a doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayed No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
Extinguishing media
Suitable extinguishing agents: Water, Foam, Carbon Dioxide (CO2), Dry Powder.
Special hazards arising from the substance or mixture
Carbon oxides, Nitrogen oxides, Sulfur oxides, Barium oxide.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
3 Composition/information on ingredients
· Chemical characterization: Substances
CAS: 6211-24-1
Barium Diphenylamine Sulphonate
< = 100 %
4 First-aid measures

5 Barium Diphenylamine Sulphonate – Fire-fighting measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions: Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralizing agent.
Dispose contaminated material as waste according to section 13. Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment. See Section 13 for disposal information.
Protective Action Criteria for Chemicals
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols.
Information about protection against explosions and fires: Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: Keep receptacle tightly sealed.
Specific end use(s) No further relevant information available.
· Additional information about design of technical systems: No further data; see section 7.

6 Barium Diphenylamine Sulphonate – Accidental release measures
· PAC-1:
CAS: 6211-24-1
Barium Diphenylamine Sulphonate
6.9 mg/m³
· PAC-2:
CAS: 6211-24-1
Barium Diphenylamine Sulphonate
850 mg/m³
· PAC-3:
CAS: 6211-24-1
Barium Diphenylamine Sulphonate
5,100 mg/m³
7 Handling and storage

8 Exposure controls/personal protection
·
Advice for firefighters
·
Protective equipment: Mouth respiratory protective device.
· Control parameters
·
Additional information: The lists that were valid during the creation were used as basis.
·
Exposure controls
·
Personal protective equipment:
·
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
· Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air.
· Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
· Eye protection:
·
Body protection: Protective work clothing
Reactivity No further relevant information available.
Chemical stability: The product is chemically stable under standard ambient conditions.
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Possibility of hazardous reactions Generates dangerous gases or fumes with: Acids

9 Barium Diphenylamine Sulphonate – Physical and chemical properties
·
Information on basic physical and chemical properties
·
General Information
·
Appearance:
Form: Crystalline Powder
Color: Off white
·
Odor: Odorless
·
Odor threshold: Not determined.
· pH-value at 20 °C (68 °F):
5.9
· Change in condition
Melting point/Melting range: Boiling point/Boiling range:
299 – 301 °C
No data available.
· Flash point:
Not applicable.
· Flammability (solid, gaseous):
Not applicable.
· Decomposition temperature:
Not determined.
· Ignition temperature:
No data available.
· Danger of explosion:
No data available.
· Explosion limits: Lower:
Upper:
Not determined. Not determined.
· Vapor pressure at 20 °C (68 °F):
No data available.
·
Density at 20 °C (68 °F):
·
Relative density
·
Vapor density
·
Evaporation rate
1 g/cm³
Not determined.
Not determined. Not determined.
· Solubility in / Miscibility with Water:
Soluble..
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity: Dynamic: Kinematic:
Not determined. Not determined.
· Other information
No further relevant information available.

10 Barium Diphenylamine Sulphonate – Stability and reactivity
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin: Caustic effect on skin and mucous membranes.
on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitization: No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations: Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach.
Carcinogenic categories
Toxicity
Aquatic toxicity: No further relevant information available.
Persistence and degradability No further relevant information available.
Behavior in environmental systems:
Bioaccumulative potential No further relevant information available.
Mobility in soil No further relevant information available.
Additional ecological information:
General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Rinse off of bigger amounts into drains or the aquatic environment may lead to decreased pH-values. A low pH- value harms aquatic organisms. In the dilution of the use-level the pH-value is considerably increased, so that after the use of the product the aqueous waste, emptied into drains, is only low water-dangerous.
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.

11 Barium Diphenylamine Sulphonate – Toxicological information
· IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
· NTP (National Toxicology Program)
None of the ingredients is listed.
· OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.

12 Ecological information
·
Conditions to avoid No further relevant information available.
·
Incompatible materials: Strong oxidizing agents.
·
Hazardous decomposition products: No dangerous decomposition products known.
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
13 Disposal considerations

14 Barium Diphenylamine Sulphonate – Transport information
·
UN-Number
·
DOT, IMDG, IATA Not Regulated.
·
UN proper shipping name
DOT Not Regulated.
IMDG, IATA Not Regulated.
·
Transport hazard class(es)
·
DOT
·
Class Not Regulated.
·
Label
·
IMDG, IATA
·
Class Not Regulated.
·
Label
·
Packing group
·
DOT, IMDG, IATA Not Regulated.
·
Environmental hazards:
·
Marine pollutant: No
·
Special precautions for user Not Regulated.
·
Hazard identification number (Kemler code): Not Regulated.
·
EMS Number: Not Regulated.
·
Segregation groups Not Regulated.
·
Stowage Category Not Regulated.
·
Stowage Code Not Regulated.
· Other adverse effects No further relevant information available.
Safety, health and environmental regulations/legislation specific for the substance or mixture
No further relevant information available.
Sara
· Proposition 65
· Carcinogenic categories
· Segregation Code Not Regulated.
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
·
Transport/Additional information:
·
DOT
·
Quantity limitations Not Regulated.
·
IMDG
·
Limited quantities (LQ) Not Regulated.
·
Excepted quantities (EQ) Not Regulated.
UN “Model Regulation”: Not Regulated.

15 Regulatory information
· Section 355 (extremely hazardous substances):
None of the ingredients is listed.
· Section 313 (Specific toxic chemical listings):
All ingredients are listed.
· TSCA (Toxic Substances Control Act):
Barium Diphenylamine Sulfonate
ACTIVE
· Hazardous Air Pollutants
None of the ingredients is listed.
· Chemicals known to cause cancer:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
· EPA (Environmental Protection Agency)
None of the ingredients is listed.

This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
Department issuing SDS: Environment protection department.
Date of preparation / last revision
Creation date for SDS 10/01/2022. STN
Revision 1.0 17/05/2023 reviewed SDS for accuracy. S.T.N.
Revision 1.1 07/03/2025 reviewed SDS for accuracy. S.T.N.
· TLV (Threshold Limit Value)
None of the ingredients is listed.
· NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
·
GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms
·
Signal word Warning
· Hazard statements
Harmful if swallowed.
· Precautionary statements
Do not breathe dusts or mists. Wash thoroughly after handling.
Wear protective gloves/protective clothing/eye protection/face protection. If swallowed: Rinse mouth. Do NOT induce vomiting.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a poison center/doctor. Specific treatment (see on this label).
Wash contaminated clothing before reuse. Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
·
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
* 16 Other information