SECTION 1: CITRIC ACID ANHYDROUS – Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name CITRIC ACID ANHYDROUS
Product number 20184
Synonyms; trade names 2-HYDROXY 1,2,3 PROPANE TRICARBOXYLIC ACID,CITRIC ACID ANHYDROUS BP2003/E330/USP27,CITRIC ACID ANH FG 30-100 M,CITRIC ACID ANHYDROUS
F6000,CITRIC ACID ANHYDROUS N1560,CITRIC ACID 0AQ FCC ed7,CITRIC ACID
WV,CITRIC ACID 0AQ,CITRIC ACID WV GRAN,CITRIC ACID ANH E330 12-40M LT,CITRIC
ACID ANH E330 16-40M YX
REACH registration number 01-2119457026-42
CAS number 77-92-9
EC number 201-069-1
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Food industry Cosmetics Industrial application
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification
Physical hazards Not Classified
Health hazards Eye Irrit. 2 – H319
Environmental hazards Not Classified
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CITRIC ACID ANHYDROUS
Classification (67/548/EEC or
1999/45/EC)
Xi; R36
Environmental The product is not expected to be hazardous to the environment. 2.2. Label elements
EC number
Pictogram
Signal word
Hazard statements
Precautionary statements 2.3. Other hazards
201-069-1
Warning
H319 Causes serious eye irritation.
P264 Wash contaminated skin thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
This substance is not classified as PBT or vPvB according to current EU criteria.
SECTION 3: CITRIC ACID ANHYDROUS – Composition/information on ingredients
3.1. Substances
Product name CITRIC ACID ANHYDROUS
REACH registration number 01-2119457026-42
CAS number 77-92-9
EC number 201-069-1
Composition comments The data shown are in accordance with the latest EC Directives.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation Move affected person to fresh air at once. Get medical attention if any discomfort continues.
Ingestion Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Rinse mouth thoroughly with water. Give plenty of water to drink. Get medical
attention if any discomfort continues.
Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention if any discomfort continues.
Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort
continues.
4.2. Most important symptoms and effects, both acute and delayed
Eye contact Irritation of eyes and mucous membranes.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor No specific recommendations. If in doubt, get medical attention promptly. 2/7
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SECTION 5: CITRIC ACID ANHYDROUS – Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.
Unsuitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.
5.2. Special hazards arising from the substance or mixture Specific hazards Oxides of the following substances: Carbon. 5.3. Advice for firefighters
Special protective equipment for firefighters
Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Follow precautions for safe handling described in this safety data sheet. Avoid contact with skin and eyes. Avoid generation and spreading of dust. Avoid inhalation of dust. Provide
adequate ventilation.
6.2. Environmental precautions
Environmental precautions Spillages or uncontrolled discharges into watercourses must be reported immediately to the Environmental Agency or other appropriate regulatory body.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up Remove spillage with vacuum cleaner. If not possible, collect spillage with shovel, broom or the like. Flush contaminated area with plenty of water. Collect and place in suitable waste
disposal containers and seal securely. For waste disposal, see Section 13.
6.4. Reference to other sections
Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet.
SECTION 7: CITRIC ACID ANHYDROUS – Handling and storage
7.1. Precautions for safe handling
Usage precautions Avoid contact with skin and eyes. Provide adequate ventilation. Avoid generation and spreading of dust. Avoid inhalation of dust.
7.2. Conditions for safe storage, including any incompatibilities
Storage precautions Keep container tightly closed. Keep only in the original container. Store in closed original container at temperatures between 5°C and 30°C.
7.3. Specific end use(s)
Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: Exposure Controls/personal protection
8.1. Control parameters
Occupational exposure limits
Long-term exposure limit (8-hour TWA): WEL 4 mg/m³
Short-term exposure limit (15-minute): WEL 10 mg/m³
WEL = Workplace Exposure Limit
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Ingredient comments WEL = Workplace Exposure Limits
PNEC – Fresh water; 0.44 mg/l
– Marine water; 0.044 mg/l
8.2. Exposure controls
Protective equipment
Appropriate engineering controls
Provide adequate ventilation. Avoid inhalation of dust. Observe any occupational exposure limits for the product or ingredients.
Eye/face protection The following protection should be worn: Chemical splash goggles.
Hand protection Use protective gloves. The most suitable glove should be chosen in consultation with the glove supplier/manufacturer, who can provide information about the breakthrough time of the
glove material.
Other skin and body protection
Wear rubber apron. Wear rubber footwear.
Hygiene measures Provide eyewash station and safety shower. Wash hands at the end of each work shift and before eating, smoking and using the toilet. Remove contaminated clothing and wash the skin
thoroughly with soap and water after work. Contaminated clothing should be placed in a
closed container for disposal or decontamination.
Respiratory protection If ventilation is inadequate, suitable respiratory protection must be worn.
SECTION 9: Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Appearance Crystalline powder.
Colour White.
Odour Odourless.
pH pH (diluted solution): 1.8 5
Melting point 153°C
Relative density 1.665 @ °C
Bulk density 400 – 1300 kg/m³
Solubility(ies) 59 – 80 @ °C Soluble in water. Soluble in the following materials: Ethanol. Partition coefficient : -1.72
Auto-ignition temperature 345°C
9.2. Other information
Other information Not determined.
SECTION 10: CITRIC ACID ANHYDROUS – Stability and reactivity
10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product. 10.2. Chemical stability
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Stability Stable at normal ambient temperatures and when used as recommended. 10.3. Possibility of hazardous reactions
Possibility of hazardous reactions
10.4. Conditions to avoid
Not determined.
Conditions to avoid Avoid excessive heat for prolonged periods of time. Avoid generation and spreading of dust. 10.5. Incompatible materials
Materials to avoid Strong alkalis. Strong oxidising agents.
10.6. Hazardous decomposition products
Hazardous decomposition products
Oxides of carbon. Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.
SECTION 11: Toxicological information
11.1. Information on toxicological effects Acute toxicity – dermal
Acute toxicity dermal (LD₅₀ mg/kg)
2,000
Inhalation May cause respiratory system irritation.
Ingestion May cause discomfort if swallowed.
Skin contact Powder may irritate skin.
Eye contact Irritating to eyes.
SECTION 12: CITRIC ACID ANHYDROUS – Ecological Information
Ecotoxicity The product components are not classified as environmentally hazardous. However, large or frequent spills may have hazardous effects on the environment.
12.1. Toxicity
Toxicity Not considered toxic to fish.
Acute toxicity – fish LC₅₀, 96 hours: 440-706 mg/l, Fish
12.2. Persistence and degradability
Persistence and degradability The product is readily biodegradable.
Biological oxygen demand 526 g O₂/g substance
Chemical oxygen demand 728 g O₂/g substance
12.3. Bioaccumulative potential
Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating. Partition coefficient : -1.72
12.4. Mobility in soil
Mobility The product is soluble in water.
12.5. Results of PBT and vPvB assessment
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Results of PBT and vPvB assessment
12.6. Other adverse effects
This product does not contain any substances classified as PBT or vPvB.
Cod 728mg/g
Other adverse effects Not determined.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
General information Waste should be treated as controlled waste. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority.
Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority.
SECTION 14: CITRIC ACID ANHYDROUS – Transport information
General The product is not covered by international regulations on the transport of dangerous goods (IMDG, IATA, ADR/RID).
14.1. UN number
No information required.
14.2. UN proper shipping name
No information required.
14.3. Transport hazard class(es)
No information required.
14.4. Packing group
No information required.
14.5. Environmental hazards
Environmentally hazardous substance/marine pollutant
No.
14.6. Special precautions for user
No information required.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
No information required.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009 No. 716).
Control of Substances Hazardous to Health Regulations 2002 (as amended).
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EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Guidance CHIP for everyone HSG228.
Workplace Exposure Limits EH40.
Safety Data Sheets for Substances and Preparations.
15.2. Chemical safety assessment
A chemical safety assessment has been carried out.
Inventories
EU – EINECS/ELINCS
All the ingredients are listed or exempt.
Canada – DSL/NDSL
DSL
SECTION 16: CITRIC ACID ANHYDROUS – Other information
Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision. Revision date 11/05/2015
Revision 02
SDS number 20184
SDS status Approved.
Signature Jitendra Panchal
Risk phrases in full R36 Irritating to eyes.
Hazard statements in full H319 Causes serious eye irritation.
Disclaimer
The information stated above is considered to be correct, but does not claim to be inclusive and shall only be used as a guideline. The information provided by this document is confirmed by our continuous updating of knowledge and adheres to the products appropriate safety precautions. It does not represent any guarantee of the product’s
properties. RLS Chemicals and its Associates shall not be held accountable for any damage’s consequent of handling the above product.
