1. IDENTIFICATION
Product Name: n-Propyl alcohol
CAS#: 71-23-8
RTECS: UH8225000
TSCA: TSCA 8(b) inventory: n-Propyl alcohol
CI#: Not applicable.
Synonym: 1-Propanol, n-Propanol; n-Propyl alcohol (Certified/Peroxide-Free/Sequencing)
Chemical Name: Propanol
Chemical Formula: CH3 CH2 CH2 OH
Recommended Use : Laboratory chemicals
2. n Propanol –Â HAZARDS IDENTIFICATION
DANGER!
Emergency Overview
Flammable liquid and vapor. Risk of serious damage to eyes. Vapors may cause drowsiness and dizziness. May cause skin and
respiratory tract irritation. Aspiration hazard if swallowed – can enter lungs and cause damage.
Appearance Clear
Physical State Liquid
odor Alcohol-like
Target Organs – Eyes, Central nervous system (CNS), Blood, Liver
Potential Health Effects
Acute Effects
Principle Routes of Exposure
Eyes
Risk of serious damage to eyes.
Skin
May cause irritation. May be harmful in contact with skin.
Inhalation
SDS: n-Propanol Page: 1
Inhalation may cause central nervous system effects. May cause irritation of respiratory tract. May be harmful if inhaled.
Ingestion Chronic Effects
Aspiration hazard. May be harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.
Chronic Effects
Tumorigenic effects have been reported in experimental animals Experiments have shown reproductive toxicity effects on laboratory
animals. May cause adverse liver effects.
Aggravated Medical Conditions
Central nervous system disorders. Gastrointestinal tract. Preexisting eye disorders. Skin disorders.
3. COMPOSITION
Name CAS # % by Weight
{n-}Propyl alcohol 71-23-8 100
Toxicological Data on Ingredients: n-Propyl alcohol: ORAL (LD50): Acute: 1870 mg/kg [Rat.]. 6800 mg/kg [Mouse]. DERMAL
(LD50): Acute: 4060 mg/kg [Rabbit.]. VAPOR (LC50): Acute: 67882.3 ppm 4 hour(s) [Mouse].
4. n Propanol – FIRST AID MEASURES
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Immediate medical attention is required.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes. Get medical attention immediately if symptoms occur.
Inhalation
Move to fresh air. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with a respiratory medical device. Get medical attention immediately if symptoms occur.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is
difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical attention.
Ingestion
Do not induce vomiting. Obtain medical attention.
Notes to Physician
Treat symptomatically.
5. FIRE FIGHTING MEASURES
Flammability of the Product: Flammable.
Auto-Ignition Temperature: 371°C (699.8°F)
Flash Points: CLOSED CUP: 15°C (59°F). OPEN CUP: 27.2°C (81°F) (Cleveland).
Flammable Limits: LOWER: 2.1% UPPER: 13.5%
Products of Combustion: These products are carbon oxides (CO, CO2).
Fire Hazards in Presence of Various Substances: Highly flammable in presence of open flames and sparks, of heat, of oxidizing
materials.
SDS: n-Propanol Page: 2
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of
static discharge: Not available.
Fire Fighting Media and Instructions:
Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam,
water spray or fog.
Special Remarks on Fire Hazards:
Explosive in the form of vapor when exposed to heat or flame. Vapor may travel considerable distance to source of ignition and
flash back. When heated to decomposition it emits acrid smoke and irritating fumes. CAUTION: MAY BURN WITH NEAR
INVISIBLE FLAME
Special Remarks on Explosion Hazards: Not available.
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear
NFPA HEALTH: 1 FLAMMABILITY: 3 INSTABILITY: 0 PHYSICAL HAZARDS: N/A
6. n Propanol – ACCIDENTAL RELEASE MEASURES
Personal Precautions
Use personal protective equipment. Remove all sources of ignition. Take precautionary measures against static discharges. Avoid
contact with skin, eyes and clothing.
Environmental Precautions
Should not be released into the environment.
Methods for Containment and Clean Up
Remove all sources of ignition. Soak up with inert absorbent material. Take precautionary measures against static discharges. Keep
in suitable and closed containers for disposal.
7. HANDLING AND STORAGE
Precautions:
Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe
gas/fumes/ vapor/spray. In case of insufficient ventilation, wear suitable respiratory equipment If ingested, seek medical advice
immediately and show the container or the label. Avoid contact with skin and eyes Keep away from incompatibles such as oxidizing
agents, acids.
Storage:
Flammable materials should be stored in a separate safety storage cabinet or room. Keep away from heat. Keep away from sources
of ignition. Keep container tightly closed. Keep in a cool, well-ventilated place. Ground all equipment containing material. A
refrigerated room would be preferable for materials with a flash point lower than 37.8°C (100°F).
8. EXPOSURE CONTROLS AND PERSONAL PROECTION
Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal Protection:
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of
the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.
SDS: n-Propanol Page: 3
Exposure Limits:
TWA: 200 STEL: 250 (ppm) from ACGIH (TLV) [1995] TWA: 492 STEL: 614 (mg/m3) from ACGIH [1995] Consult local
authorities for acceptable exposure limits.
9. n Propanol – PHYSICAL AND CHEMICAL PROPERTIES
Physical state and appearance: Liquid. (Liquid.)
Odor: Alcohol like.
Taste: Not available.
Molecular Weight: 60.1 g/mole
Color: Colorless.
pH (1% soln/water): 7 [Neutral.]
Boiling Point: 97.22°C (207°F)
Melting Point: -126.2°C (-195.2°F)
Critical Temperature: Not available.
Specific Gravity: 0.8053 (Water = 1)
Vapor Pressure: 14.9 mm of Hg (@ 20°C)
Vapor Density: 2.07 (Air = 1)
Volatility: Not available.
Odor Threshold: 5.3 ppm
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, methanol, diethyl ether.
Solubility: Easily soluble in cold water, hot water, methanol, diethyl ether.
10. STABILITY AND REACTIVITY
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances: Reactive with oxidizing agents, acids.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity: Not available
.
Special Remarks on Corrosivity: Not available.
Polymerization: No.
Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2)
SDS: n-Propanol Page: 4
11. n Propanol – TOXICOLOGICAL INFORMATION
Acute Toxicity
COMPONENT LD50 ORAL LD50 DERMAL LC50 INHALATION
n-PROPYL ALCOHOL 1870 mg/kg (Rat)not listed 13548 ppm (Rat) 4 h
Irritation
Severe eye irritant
Toxicologically Synergistic Products
No information available.
Chronic Toxicity
Carcinogenicity
There are no known carcinogenic chemicals in this product
Sensitization
No information available
Mutagenic Effects
Mutatagenic effects have occured in microorganisms.
Reproductive Effects
Experiments have shown reproductive toxicity effects on laboratory animals.
Developmental Effects
Developmental effects have occurred in experimental animals.
Teratogenicity
Teratogenic effects have occurred in experimental animals
Other Adverse Effects
Tumorigenic effects have been reported in experimental animals.. See actual entry in RTECS for complete information.
Endocrine Disruptor Information
No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are more toxic.
Special Remarks on the Products of Biodegradation: Not available.
Mobility
Component log Pow
n-Propyl alcohol 0.25 – 0.34
13. n Propanol – DISPOSAL CONSIDERATIONS
Page: 5
Waste Disposal Methods
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste
generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification
14. TRANSPORT INFORMATION
DOT
UN No. UN 1274
Proper shipping name: n_Propanol
Hazard Class 3
Packing Group II
TDG
Un No. UN 1274
Proper shipping name n-Propanol
Hazard Class 3
Packing Group II
IATA & IMDG/IMO
UN No UN 1274
Proper Shipping name: n-Propanol
Hazard Class 3
Packing Group II
Marine Pollutant: No
15. n Propanol – REGULATORY INFORMATION
Federal and State Regulations:
Pennsylvania RTK: n-Propyl alcohol Massachusetts RTK: n-Propyl alcohol TSCA 8(b) inventory: n-Propyl alcohol
Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Classifications:
WHMIS (Canada):
CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). CLASS D-2B: Material causing other toxic effects
(TOXIC).
DSCL (EEC):
R11- Highly flammable. R38- Irritating to skin. R41- Risk of serious damage to eyes.
HMIS (U.S.A.):
Health Hazard: 1
Fire Hazard: 3 Reactivity: 0
Personal Protection: h
National Fire Protection Association (U.S.A.):
Health: 1
Flammability: 3
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when
ventilation is inadequate. Splash goggles.
16. OTHER INFORMATION
Disclaimer
The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal
and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other material or in any process, unless specified in
Disclaimer
The information stated above is considered to be correct, but does not claim to be inclusive and shall only be used as a guideline. The information provided by this document is confirmed by our continuous updating of knowledge and adheres to the products appropriate safety precautions. It does not represent any guarantee of the product’s
properties. RLS Chemicals and its Associates shall not be held accountable for any damage’s consequent of handling the above product
