Phenol 80% (liquified) – Identification of Product
Chemical Code: RLS-SOL-P01 to P02
Chemical Name: Phenol 80% Liquified
Chemical Grade:
Chemical Formula: C₆H₆O
Chemical Weight: 94,11 g/mol
CAS No: 108-95-2
Chemical Synonyms: Phenol
Phenol 80% (liquified) – Hazards Identification
REACH No: 01-2119471329-32-XXXX
Signal Word: Danger
Supplemental Hazard Information:
Additional Hazard Information: This substance/mixture contains no components considered to be either persistent, bio-accumulative and toxic (PBT), or very persistent and very bio-accumulative (vPvB) at levels of 0.1% or higher. Vesicant., Rapidly absorbed through
skin.
Phenol 80% (liquified) – Hazards statements
H301 Toxic if swallowed.
H301 + H311 + H331 – Toxic if swallowed, in contact with skin or if inhaled
H311 – Toxic in contact with skin.
H314 – Causes severe skin burns and eye damage.
H315 – Causes skin irritation.
H319 – Causes serious eye irritation.
H331 – Toxic if inhaled.
H341 – Suspected of causing genetic defects.
H373 – May cause damage to organs through prolonged or repeated exposure.
H411 – Toxic to aquatic life with long lasting effects.
Phenol 80% (liquified) – Precautionary statements
P260 – Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P280 – Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331 + P310 – IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/ physician.
P303 + P361 + P353 – IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 + P310 – IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Phenol 80% (liquified) – Composition of Chemical
Chemical Formula: C₆H₆O
EC No 1272/2008: 01-2119471329-32-XXXX
Phenol 80% (liquified) – First Aid Measures
General Advice: Consult a physician. Show this safety data sheet to the doctor in attendance.
If: Inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
If: Skin Contact: Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
If: Eye Contac: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If: Swallowed: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Important Symptoms: The most important known symptoms and effects are described in the labeling section.
Immediate Medical Attention: No Data Available Firefighting Measures
Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Hazards Arising: Carbon oxides
Advice for Firefighters: Wear self-contained breathing apparatus for firefighting if necessary.
Info for Firefighting: No Data Available
Phenol 80% (liquified) – Accidental Release Measures
Personal Precautions: Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas.
Environmental Precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
Method for Containment: Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal.
Handling and Storage
Personal Precautions: Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Environmental Precautions: Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature 2 – 8 °C. Handle and store under inert gas. Light sensitive. Storage class (TRGS 510): Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials.
Exposure Controls | Personal Protection
Derived No Effect Level (DNEL)
Workers | Application Area | Exposure Routes | Health Effect | Value
No Data Available
Consumers | Application Area | Exposure Routes | Health Effect | Value
No Data Available
Predicted No Effect Concentration (PNEC)
No Data Available
Engineering Controls: Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Eye/Face Protection: Tightly fitting safety goggles. Face-shield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin Protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove’s outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Full contact
Material: butyl-rubber
Minimum layer thickness: 0,3 mm
Break through time: 480 min
Material tested: Butoject® (KCL 897 / Size M)
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 120 min
Material tested: Dermatril® (KCL 740 / Size M)
data source: KCL GmbH, D-36124 test method: EN374
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Body Protection: Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory Protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Physical and Chemical Properties
Appearance: Colourless to Brownish liquid
Odour: No Data Available
Odour Threshold: No Data Available
pH: No Data Available
Melting Point: Melting Point/Range: 40 – 42 °C
Boiling Point: 182 °C at 1.013 hPaFlash Point: 79 °C – Closed Cup
Evaporation: No Data Available
Flammability: No Data Available
Upper/Lower Flammability or Explosive Limits: Upper explosion limit: 8,6 %(V) Lower explosion limit: 1,7 %(V)
Vapour pressure: 0,48 hPa at 20 °C 6,203 hPa at 55 °C
Vapour density: No Data Available
Relative density: 1,07 g/cm3 at 25 °C
Water solubility: No Data Available
Partition Coefficien: No Data Available
Auto-ignition Temperature: 715 °C
Decomposition Temperature: No Data Available
Viscosity: No Data Available
Explosive properties: No Data Available
Oxidizing properties: No Data Available
Other Safety Info: No Data Available
Stability and Reactivity
Reactivity: No Data Available
Chemical Stability: Stable under recommended storage conditions.
Possibility of hazardous reactions: No Data Available
Conditions to Avoid: No Data Available
Incompatible Materials: Strong bases, Strong oxidizing agents, Strong acids.
Hazardous Decomposition Products: Other decomposition products – No Data Available
Toxicological Information
Acute Toxicity: No Data Available
Skin Corrosion/Irritation: No Data Available
Serious Eye damage | Eye Irritation: No Data Available
Cell Mutagenicity: No Data Available
Carcinogenicity: IARC: 3 – Group 3: Not classifiable as to its carcinogenicity to humans (Phenol).
Reproductive toxicity: No Data Available Specific Target Organ Toxicity – Single Exposure: No Data Available
Specific Target Organ Toxicity – Repeated Exposure: No Data Available
Aspiration Hazard: No Data Available
Ecological Information
Ecological Toxicity: No Data Available
Ecological Persistence and degradability: No Data Available
Bio-accumulative Potential: No Data Available
Mobility in Soil: No Data Available
Results of PBT and vPvB Assessment: This substance/mixture contains no components considered to be either persistent, bio-accumulative and toxic (PBT), or very persistent and very bio-accumulative (vPvB) at levels of 0.1% or higher.
Other Adverse Effect: Toxic to aquatic life with long lasting effects.
Disposal Considerations
Waste Treatment Methods: Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.
Transport Information
UN Number: ADR/RID: 2821
IMDG: 2821
IATA: 2821
UN Shipping Hazard: ADR/RID: PHENOL SOLUTION
IMDG: PHENOL SOLUTION
IATA: Phenol solution
Transport Hazard Class: ADR/RID: 6.1
IMDG: 6.1
IATA: 6.1
Packaging Group: ADR/RID: II
IMDG: II
IATA: II Environmental Hazards: ADR/RID: yes
IMDG Marine pollutant: yes
IATA: no
Special Precautions: No Data Available
Regulatory Information
Safety, Health and environmental regulations: This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Chemical Safety Assessment: For this product a chemical safety assessment was not carried out.
Additional Info: RTECS: Not Available
Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea.
Disclaimer
The information stated above is considered to be correct, but does not claim to be inclusive and shall only be used as a guideline. The information provided by this document is confirmed by our continuous updating of knowledge and adheres to the products appropriate safety precautions. It does not represent any guarantee of the product’s
properties. RLS Chemicals and its Associates shall not be held accountable for any damage’s consequent of handling the above product