Pine Oil

Pine Oil

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION 

Product name : Pine OIl 

Company 

REFLECTA  LAB SUPPLIES 

SECTION 2 Pine Oil – HAZARDS IDENTIFICATION GHS-Classification 

Flammable liquids, Category 4 

Skin irritation, Category 2 

Eye irritation, Category 2A 

Skin sensitisation, Category 1 

Aspiration hazard, Category 1 

GHS-Labelling 

Symbol(s) : 

Signal word : Danger

Pine Oil 

Hazard statements : H227: Combustible liquid. 

H304: May be fatal if swallowed and enters airways. 

H315: Causes skin irritation. 

H317: May cause an allergic skin reaction. 

H319: Causes serious eye irritation. 

Precautionary statements : P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking. 

P280: Wear protective gloves/ eye protection/ face protection. 

P301 + P310: IF SWALLOWED: Immediately call a POISON 

CENTER or doctor/ physician. 

P302 + P352: IF ON SKIN: Wash with plenty of soap and water. 

P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for 

several minutes. Remove contact lenses, if present and easy to do. 

Continue rinsing. 

P331: Do NOT induce vomiting. 

Carcinogenicity: 

No component of this product present at levels greater than or equal to 0.1% is identified as  probable, possible or confirmed human carcinogen by IARC. 

No component of this product present at levels greater than or equal to 0.1% is identified as a  carcinogen or potential carcinogen by OSHA. 

No component of this product present at levels greater than or equal to 0.1% is identified as a known  or anticipated carcinogen by NTP. 

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature : Fragrance for consumer product 

Hazardous components

Component	CAS-No.
Oils, pine	8002-09-3, 8000-41-7

 

Pine Oil 

SECTION 4. Pine Oil – FIRST AID MEASURES 

First aid procedures 

Inhalation : Remove from exposure site to fresh air and keep at rest. If victim is  unconscious, remove foreign bodies from the mouth. If victim has  

stopped breathing, give artificial respiration. Obtain medical advice. 

Skin contact : Remove contaminated clothes. Wash thoroughly with water (and  soap). Contact physician if symptoms persist. 

Eye contact : Flush immediately with water for at least 15 minutes. Contact  physician if symptoms persist. 

Ingestion : Rinse mouth with water and obtain medical advice. 

SECTION 5. FIREFIGHTING MEASURES 

Flammable properties 

Flash point : 162 °F (72 °C) 

Fire fighting 

Suitable extinguishing media : Use water spray, dry chemical, carbon dioxide or appropriate foam. Protective equipment and precautions for firefighters 

Special protective equipment for  firefighters 

: Wear NIOSH approved self-contained breathing apparatus and full  protective clothing when fighting fires involving chemicals. Use  water spray to cool containers exposed to fire.

Pine Oil 

SECTION 6. ACCIDENTAL RELEASE MEASURES 

Personal precautions : Avoid inhalation and contact with skin and eyes. A self-contained breathing apparatus is recommended in case of a major spill. 

Environmental precautions : Keep away from drains, surface- and groundwater and soil. 

Methods for containment / : Clean up spillage promptly. Remove ignition sources. Provide Methods for cleaning up adequate ventilation. Avoid excessive inhalation of vapours. Gross spillages should be contained by use of sand or inert powder  

and disposed of according to the local regulations. 

SECTION 7. Pine Oil – HANDLING AND STORAGE 

Handling 

Advice on protection against fire  and explosion 

: Avoid excessive inhalation of concentrated vapors. Follow good  manufacturing practices for housekeeping and personal hygiene.  Wash any exposed skin immediately after any chemical contact,  before breaks and meals, and at the end of each work period. 

Contaminated clothing and shoes should be thoroughly  cleaned before re-use. 

If appropriate, procedures used during the handling of this material  should also be used when cleaning equipment or removing residual  chemicals from tanks or other containers, especially when steam or  hot water is used, as this may increase vapor concentrations in the  

workplace air. Where chemicals are openly handled, access should  be restricted to properly trained employees. 

Keep all heated processes at the lowest necessary temperature in  order to minimize emissions of volatile chemicals into the air. 

: Keep away from ignition sources and naked flame.

Requirements for storage areas  and containers 

Pine Oil 

: Store in a cool, dry, ventilated area away from heat sources.  Keep containers upright and tightly closed when not in use. 

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters 

Components	Listed by	Value type	Exposure  limit(s)
3-Cyclohexene-1- methanol,  .alpha.,.alpha.,4-  trimethyl	USA. ACGIH Threshold Limit Values (TLV)	8-hour, time-weighted average	20 ppm
Cyclohexene, 1-  methyl-4-(1-  methylethenyl)-,  Cyclohexene, 1-  methyl-4-(1-  methylethenyl)-,  (4R)-, Cyclohexene, 1-methyl-4-(1-  methylethenyl)-,  (4S)-	USA. Workplace Environmental Exposure Levels (WEEL)	8-hr TWA	30 ppm

 

Engineering measures 

Engineering measures : Where feasible, isolate mixing rooms and other areas where this material is used or openly handled. Maintain these areas under 

negative air pressure relative to the rest of the plant. 

Where feasible, use closed systems to transfer and process this 

material 

Personal protective equipment 

Eye protection : Use tight-fitting goggles, face shield or safety glasses with side

Pine Oil 

shields if eye contact might occur. 

Hand protection : Avoid skin contact. Use chemically resistant gloves. 

Respiratory protection : Use local exhaust ventilation around open tanks and other open sources of potential exposures in order to avoid excessive inhalation, 

including places where this material is openly weighed or measured. 

In addition, use general dilution ventilation of the work area to 

eliminate or reduce possible worker exposures. 

No respiratory protection is required during normal operations in a 

workplace where engineering controls such as adequate ventilation, 

etc. are sufficient. 

If engineering controls and safe work practices are not sufficient, an 

approved, properly fitted respirator with organic vapor cartridges or 

canisters and particulate filters should be used: 

a)while engineering controls and appropriate safe work practices 

and/or procedures are being implemented; or 

b)during short term maintenance procedures when engineering 

controls are not in normal operation or are not sufficient; or 

c)if normal operational workplace vapor concentration in the air is 

increased due to heat ; 

d)during emergencies; or 

e)if engineering controls and operational practices are not sufficient 

to reduce airborne concentrations below an established occupational 

exposure limit. 

Hygiene measures : To the extent deemed appropriate, implement pre-placement and regularly scheduled ascertainment of symptoms and spirometry 

testing of lung function for workers who are regularly exposed to 

this material. 

To the extent deemed appropriate, use an experienced air sampling 

expert to identify and measure volatile chemicals that could be 

present in the workplace air to determine potential exposures and to 

ensure the continuing effectiveness of engineering controls and 

operational practices to minimize exposure.

Pine Oil 

Protective measures : In December 2003, the National Institute for Occupational Safety and Health (“NIOSH”) published an Alert on preventing lung 

disease in workers who use or make flavorings [NIOSH Publication 

Number 2004-110]. 

In August 2004, the United States Flavor and Extract Manufacturers 

Association (FEMA) issued a report entitled “Respiratory Safety in 

the Flavor Manufacturing Workplace”. 

Both of these reports provide recommendations for reducing 

employee exposure and for medical surveillance in the workplace. 

The recommendations in these reports are generally applicable to the 

use of any chemical in the workplace and you are strongly urged to 

review both of these reports. 

The report published by FEMA also contains a list of “high priority” 

chemicals. If any of these chemicals are present in this product at a 

concentration >= 1.0% due to an intentional addition by IFF, the 

chemical(s) will be identified in this safety data sheet. 

SECTION 9. Pine Oil – PHYSICAL AND CHEMICAL PROPERTIES 

Appearance 

Physical state : liquid 

Appearance : CLEAR LIQUID 

Colour : colorless to pale yellow 

Odour : conforms to standard 

Safety data 

Flash point : 162 °F (72 °C) 

Vapour pressure : 5.33 hPa (5.33 hPa) 

Note: Calculated

Pine Oil 

Relative density (20 °C) : 0.9240 – 0.9310 

SECTION 10. STABILITY AND REACTIVITY Conditions to avoid : Remarks: Direct sources of heat. 

Chemical stability : Remarks: Presents no significant reactivity hazard, by itself or in  contact with water. Avoid contact with strong acids, alkali or  

oxidizing agents. 

Hazardous decomposition products : Note: Carbon monoxide and unidentified organic compounds may  be formed during combustion. 

SECTION 11. TOXICOLOGICAL INFORMATION 

Acute oral toxicity : Acute toxicity estimate 

Dose: 2,027 mg/kg 

Method: Calculation method 

Acute oral toxicity (Component) : Component: 98-55-5 

LD50 Rat 

Dose: 4,300 mg/kg 

Method: OECD Test Guideline 401 

Remarks: RIFM 

Component: 138-86-3 

LD50 Rat 

Dose: 5,300 mg/kg 

Component: 586-62-9 

LD50 Rat 

Dose: 3,840 mg/kg

Pine Oil 

Remarks: RIFM 

Component: 562-74-3 

LD50 Rat 

Dose: 1,300 mg/kg 

Remarks: RIFM 

Component: 470-82-6 

LD50 Rat 

Dose: 2,480 mg/kg 

Remarks: Supplier 

Acute dermal toxicity : Acute toxicity estimate Dose: 3,733 mg/kg 

Method: Calculation method 

Acute dermal  

toxicity (Component) 

: Component: 98-55-5 

LD50 Rabbit 

Dose: > 3,000 mg/kg 

Method: OECD Test Guideline 402 

Component: 138-86-3 

LD50 Rabbit 

Dose: > 5,000 mg/kg 

Component: 586-62-9 

LD50 Rabbit 

Dose: > 5,000 mg/kg 

Component: 562-74-3 

LD50 Rabbit 

Dose: 2,500 mg/kg 

Component: 470-82-6 

LD50 Rabbit 

Dose: > 5,000 mg/kg

Pine Oil 

Skin irritation (Component) : Component: 98-55-5 Rabbit 

Result: Skin irritation 

Method: OECD Test Guideline 404 

Exposure time: 24 h 

Component: 138-86-3 

Rabbit 

Result: Skin irritation 

Exposure time: 24 h 

Test substance:(undiluted) 

human 

Result: No skin irritation 

Method: closed patch test 

Exposure time: 48 h 

Component: 586-62-9 

human 

Result: No skin irritation 

Method: closed patch test 

Exposure time: 48 h 

Rabbit 

Result: No skin irritation 

Exposure time: 24 h 

Component: 562-74-3 

Rabbit 

Result: Skin irritation 

Exposure time: 24 h 

Component: 470-82-6 

Rabbit 

Result: No skin irritation 

Exposure time: 24 h 

Eye irritation(Component) : Component: 98-55-5 Rabbit

Pine Oil 

Result: Eye irritation 

Method: OECD Test Guideline 405 

Exposure time: 72 h 

Sensitisation (Component) : Component: 98-55-5 

LLNA Rat 

Result: causes no sensitization 

Method: OECD Test Guideline 429 

Component: 138-86-3 

LLNA Mouse 

Result: Causes sensitisation. 

Test substance: 22% in ethanol/DEP (75:25) 

maximisation study human 

Result: causes no sensitization 

Test substance: 20% in petrolatum 

Component: 586-62-9 

maximisation study human 

Result: Did not cause sensitisation on laboratory animals. 

Test substance: 20% in petrolatum 

Component: 562-74-3 

human 

Result: causes no sensitization 

Repeated dose  

toxicity(Component) 

: Component: 98-55-5 

OralRat 

NOEL: > 314 mg/kg 

Method: OECD Test Guideline 408 

Remarks: No adverse effect has been observed in chronic toxicity tests. 

Component: 138-86-3 

Component: 586-62-9

Carcinogenicity (Component) : 

Pine Oil 

Component: 562-74-3 Component: 98-55-5 

SECTION 12. Pine Oil – ECOLOGICAL INFORMATION 

Component: 

98-55-5 alpha-TerpineolToxicity to fish: 

semi-static test LC50 

Species: Brachydanio rerio (zebrafish) 

Dose: 70 mg/l 

Exposure time: 96 h 

Method: OECD Test Guideline 203 

Information taken from reference works and the 

literature. 

Toxicity to daphnia and other aquatic invertebrates: 

static test EC50 

Species: Daphnia magna (Water flea) 

Dose: 73 mg/l 

Exposure time: 48 h 

Method: OECD Test Guideline 202 

Information taken from reference works and the 

literature. 

Toxicity to algae: 

static testEC50 

Species: Pseudokirchneriella subcapitata (aglae) 

Dose: 68 mg/l 

Exposure time: 72 h 

Method: OECD Test Guideline 201 

Information taken from reference works and the 

literature. 

Toxicity to algae: 

static testNOEC 

Species: Pseudokirchneriella subcapitata (aglae)

Pine Oil 

Dose: 3.9 mg/l 

Exposure time: 72 h 

Method: OECD Test Guideline 201 

Information taken from reference works and the 

literature. 

Toxicity to bacteria: 

static test NOEC 

Species: activated sludge 

Dose: 25.7 mg/l 

Method: OECD Test Guideline 310 

138-86-3 Dipentene Toxicity to fish: 

LC50 

Species: 

Dose: 0.702 mg/l 

Exposure time: 96 h 

586-62-9 Terpinolene Toxicity to fish: 

LC50 

Species: 

Dose: 1.21 mg/l 

Exposure time: 96 h 

Toxicity to daphnia and other aquatic invertebrates: 

EC50 

Species: 

Dose: 1.38 mg/l 

Exposure time: 48 h 

Toxicity to daphnia and other aquatic invertebrates: 

EC50 

Species: 

Dose: 2.55 mg/l 

Exposure time: 48 h

Pine Oil 

562-74-3 4-Terpineol Toxicity to daphnia and other aquatic invertebrates: static test EC50 

Species: Daphnia magna (Water flea) 

Dose: 97 mg/l 

Exposure time: 48 h 

RIFM 

SECTION 13. Pine Oil – DISPOSAL CONSIDERATIONS 

Contaminated packaging : Place material into sealed containers and dispose of in accordance  with local, state and federal regulations. 

SECTION 14. TRANSPORT INFORMATION 

DOT Proper shipping name : Combustible liquid, n.o.s. (DIPENTENE) 

UN number : 1993 

Class : CBL 

Packing group : III 

Emergency Response : 128 

Guidebook Number 

DOT NON-BULK Not dangerous goods 

IATA UN number : 3082 

Description of the goods : ENVIRONMENTALLY HAZARDOUS 

SUBSTANCE, LIQUID, N.O.S. 

(DIPENTENE) 

Class : 9 

Packing group : III 

ICAO-Labels : 9

Pine Oil 

IMDG UN number : 3082 

Description of the goods : ENVIRONMENTALLY HAZARDOUS 

SUBSTANCE, LIQUID, N.O.S. 

(DIPENTENE) 

Class : 9 

Packing group : III 

IMDG-Labels : 9 

EmSNumber 1 : F-A 

EmSNumber 2 : S-F 

Marine pollutant : yes 

(DIPENTENE) 

SECTION 15. REGULATORY INFORMATION 

SARA 311/312 Hazards : Fire Hazard 

Acute Health Hazard 

Reportable Quantity : 

HMIS Classification : Health hazard: 1 

Flammability: 2 

Physical and chemical hazards: 0 

SECTION 16. Pine Oil – OTHER INFORMATION 

All reasonable efforts were exercised to compile this SDS in accordance with GHS SANS 10234. The SDS provides information  regarding the health, safety and environmental hazards, at the date of issue, to facilitate the safe receipt, use and handling of the  product in the workplace. RLS cannot anticipate or control all conditions under which the product may be handled, used and received in the workplace, it remains the obligation of each user, receiver or handler to, prior to usage, review this SDS in the  context within which the product will be received, handled or used in the workplace. The user, handler or receiver must ensure  that the necessary mitigating measures are in place as regards health and safety. This does not substitute the need or  requirement for any relevant risk assessments to be conducted. It further remains the responsibility of the receiver, handler or  user to communicate such information to all relevant parties that may be involved in the receipt, use or handling of the product.  Although all reasonable efforts were exercised in the compilation of this SDS, RLS does not expressly warrant the accuracy or assume any liability for the incompleteness of the information contained herein or any advice given. The product is sold and risk  passes in accordance with the specific terms and conditions of sale 

Disclaimer

The information stated above is considered to be correct, but does not claim to be inclusive and shall only be used as a guideline. The information provided by this document is confirmed by our continuous updating of knowledge and adheres to the products appropriate safety precautions. It does not represent any guarantee of the product’s
properties. RLS Chemicals and its Associates shall not be held accountable for any damage’s consequent of handling the above product.